E-Book Overview
Providing a thorough overview of leading research from internationally-recognized contributing authors, this book describes methods for the preparation and application of redox systems for organic electronic materials like transistors, photovoltaics, and batteries.
• Covers bond formation and cleavage, supramolecular systems, molecular design, and synthesis and properties• Addresses preparative methods, unique structural features, physical properties, and material applications of redox active p-conjugated systems• Offers a useful guide for both academic and industrial chemists involved with organic electronic materials• Focuses on the transition-metal-free redox systems composed of organic and organo main group compounds
E-Book Content
Organic Redox Systems Organic Redox Systems Synthesis, Properties, and Applications Edited by Tohru Nishinaga Copyright © 2016 by John Wiley & Sons, Inc. All rights reserved Published by John Wiley & Sons, Inc., Hoboken, New Jersey Published simultaneously in Canada No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per‐copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750‐8400, fax (978) 750‐4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748‐6011, fax (201) 748‐6008, or online at http://www.wiley.com/go/permissions. Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives or written sales materials. The advice and strategies contained herein may not be suitable for your situation. You should consult with a professional where appropriate. Neither the publisher nor author shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages. For general information on our other products and services or for technical support, please contact our Customer Care Department within the United States at (800) 762‐2974, outside the United States at (317) 572‐3993 or fax (317) 572‐4002. Wiley also publishes its books in a variety of electronic formats. Some content that appears in print may not be available in electronic formats. For more information about Wiley products, visit our web site at www.wiley.com. Library of Congress Cataloging‐in‐Publication Data Organic redox systems : synthesis, properties, and applications / edited by Tohru Nishinaga. pages cm Includes bibliographical references and index. ISBN 978-1-118-85874-5 (cloth) 1. Oxidation-reduction reaction. I. Nishinaga, Tohru, editor. QD716.O95O74 2016 547′.23–dc23 2015030167 Cover image courtesy of Axel Kores/Getty Cover Illustration: Courtesy of Tohru Nishinaga and Takashi Kubo Set in 10/12pt Times by SPi Global, Pondicherry, India Printed in the United States of America 10 9 8 7 6 5 4 3 2 1 1 2016 Contents LIST OF CONTRIBUTORS xv PREFACE xix 1 Introduction: Basic Concepts and a Brief History of Organic Redox Systems 1 Tohru Nishinaga 1.1 Redox Re