Hydrosilylation: A Comprehensive Review On Recent Advances

E-Book Overview

For fifty years,<EM> Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating the various aspects of Hydrosilylation has been published this century.

The aim of <EM>Hydrosilylation is to comprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades, including ca 2000 articles, patents and reviews, enables the authors to discuss the most recent aspects of hydrosilylation advances, (i.e. catalytic and synthetic) as well as to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. The key point of this monograph is to show extensive development in the application of hydrosilylation in organic and asymmetric syntheses as well as in polymer and material science.

<EM>Hydrosilylation is the definitive monograph in the area written for reseachers and industrial chemists involved in silicon chemistry, organic synthetic chemists with an interest in silicones, silane coupling agents and hybrid inorganic-organic materials; as well as researchers working on organosilicon reagents in organic and polymer chemistry. Finally, this book provides an excellent review of hydrosilylation processes and their products thus making this book a useful handbook for post-graduate students working in catalysis, organometallic chemistry as well as synthesis and the technology of fine chemicals.


E-Book Content

ADVANCES IN SILICON SCIENCE VOLUME 1 Series Editor: JANIS MATISONS School of Chemistry, Physics and Earth Sciences, Flinders University, South Australia. Advances in Silicon Science is a book series which presents reviews of the present and future trends in silicon science and will benefit those in chemistry, physics, biomedical engineering, and materials science. It is aimed at all scientists at universities and in industry who wish to keep abreast of advances in the topics covered. Series Editor Professor Janis Matisons, Nanomaterials Group, Chair of Nanotechnology, School of Chemistry, Physics and Earth Sciences, Flinders University, GPO Box 2100, Adelaide 5001 SOUTH AUSTRALIA Volume 1 Hydrosilylation: A Comprehensive Review on Recent Advances Volume Editor Professor Bogdan Marciniec Department of Organometallic Chemistry, Adam Mickiewicz University, Poznan, POLAND. For other titles published in this series, go to http://www.springer.com/series/7926 Hydrosilylation Bogdan Marciniec Editor Hydrosilylation A Comprehensive Review on Recent Advances Contributing authors Bogdan Marciniec, Hieronim Maciejewski, Cezary Pietraszuk, Piotr Pawlu´c Adam Mickiewicz University, Poland 123 Editor Prof. Dr. Bogdan Marciniec A. Mickiewicz University Faculty of Chemistry Grunwaldzka 6 60-780 Poznan Poland [email protected] Contributing authors Bogdan Marciniec Hieronim Maciejewski Cezary Pietraszuk Piotr Pawlu´c [email protected] [email protected]
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