Selected Topics In High Temperature Chemistry: Defect Chemistry Of Solids

Studies in Inorganic Chemistry Other titles in this series 1 Phosphine, Arsine and Stibine Complexes of the Transition Elements by C.A. McAuliffe and W. Levason 2 Phosphorus: An Outline of its Chemistry, Biochemistry and Technology (Second Edition) by D.E.C. Corbridge 3 Solid State Chemistry 1 9 8 2 edited by R. Metselaar, H.J.M. Heijligers and J. Schoonman 4 Gas Hydrates by E. Berecz and M. Balla-Achs 5 Sulfur: Its Significance for Chemistry, for the Geo-, Bio-, and Cosmosphere and Technology edited by A. Müller and B. Krebs 6 Phosphorus: An Outline of its Chemistry, Biochemistry and Technology (Third Edition) by D.E.C. Corbridge 7 Inorganic High Pressure Chemistry: Kinetics and Mechanisms edited by R. van Eldik 8 Graphite Fluorides by N. Watanabe, T. Nakajima and H. Touhara Studies in Inorganic Chemistry 9 Selected Topics in High Temperature Chemistry Defect Chemistry of Solids Edited by 0ivind Johannesen The Norwegian Institute of Technology, Trondheim, Norway Arnf inn G. Andersen Center for Industrial Research, Oslo, Norway Amsterdam — Oxford — New York — Tokyo 1989 ELSEVIER SCIENCE PUBLISHERS B.V. Sara Burgerhartstraat 25 P.O. Box 2 1 1 , 1000 AE Amsterdam, The Netherlands Distributors for the United States and Canada: ELSEVIER SCIENCE PUBLISHING COMPANY INC. 655, Avenue of the Americas New York, NY 10010, U.S.A. Library of Congress Cataloglng-in-Publication Data Selected topics in high temperature chemistry : defect chemistry of solids / edited by 0ivind Johannesen, Arnfinn G. Anderson. p. cm. — (Studies in inorganic chemistry ; 9) "A collection of monographs dedicated to Professor Per Kofstad on his 60th birthday, 7 December, 1989"—CIP galley. Includes bibliographical references. ISBN 0-444-88534-X 1. High temperature chemistry. 2. Crystals—Defects. 3. Solids. 4. Kofstad, Per. I. Kofstad, Per. II. Johannesen, 0ivind. III. Andersen, Arnfinn G. IV. Series. QD515.S35 1989 89-25S8G 541.3 ' 687—dc20 CIP ISBN 0-444-88534-X © Elsevier Science Publishers B.V., 1989 All rights reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, without the prior written permission of the publisher, Elsevier Science Publishers B.V./ Physical Sciences & Engineering Division, P.O. Box 330, 1000 AH Amsterdam, The Netherlands. Special regulations for readers in the USA - This publication has been registered with the Copyright Clearance Center Inc. (CCC), Salem, Massachusetts. Information can be obtained from the CCC about conditions under which photocopies of parts of this publication may be made in the USA. All other copyright questions, including photocopying outside of the USA, should be referred to the publisher. No responsibility is assumed by the Publisher for any injury and/or damage to persons or property as a matter of products liability, negligence or otherwise, or from any use or operation of any meth­ ods, products, instructions or ideas contained in the material herein. Printed in The Netherlands A Collection of Monographs Dedicated to Professor Per Kofstad on His 60th Birthday, 7 December 1989 ìO Interstitial hydroxide OH" (0H)| Interstitial water H20 Proton defects; (H20)f + Interstitial hydronium H30 Hydrated interstitial hydronium H (H 5 o 2 ): Proton-metal vacancy associate 5°2 + OH" Proton-acceptor associate Ml+OH" ( V M(° H >O>' (MlM(OH)0)X (H30): Atom and molecule defects; Interstitial hydrogen atom H