Modern Synthesis Processes And Reactivity Of Fluorinated Compounds. Progress In Fluorine Science

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E-Book Overview

<EM>Modern Synthesis Processes and Reactivity of Fluorinated Compounds focuses on the exceptional character of fluorine and fluorinated compounds. This comprehensive work explores examples taken from all classes of fluorine chemistry and illustrates the extreme reactivity of fluorinating media and the peculiar synthesis routes to fluorinated materials.

The book provides advanced and updated information on the latest synthesis routes to fluorocompounds and the involved reaction mechanisms. Special attention is given to the unique reactivity of fluorine and fluorinated media, along with the correlation of those properties to valuable applications of fluorinated compounds.


E-Book Information

  • Year: 2,016

  • Edition: 1st Edition

  • Pages: 760

  • Pages In File: 765

  • Language: English

  • Identifier: 9780128037904,9780128037409

  • Org File Size: 52,831,104

  • Extension: pdf

  • Tags: Home Books & Journals Chemistry Inorganic Chemistry Modern Synthesis Processes and Reactivity of Fluorinated Compounds

  • Toc: Content: Progress in Fluorine Science Series,Front Matter,Copyright,List of Contributors,ForewordEntitled to full textChapter One - The Cosmic Origin of Fluorine: An Astronomer's View on Fluorine Synthesis, Pages 1-6, H. Jönsson, N. RydeChapter Two - The Fluorine Atom in Health Care and Agrochemical Applications: A Contribution to Life Science, Pages 7-25, M. Braun, J. Eicher3 - Industrial Syntheses of Hydrohaloolefins and Related Products, Pages 27-69, M. Nappa, S. Peng, X. Sun4 - Electrochemical Fluorination: A Powerful Tool for the Preparation of Organofluorine Compounds, Pages 71-123, N.V. Ignat'ev5 - Once Upon a Time Was the Langlois' Reagent: A “Sleeping Beauty”, Pages 125-140, B.R. Langlois6 - Toward CF3S Group: From Trifluoromethylation of Sulfides to Direct Trifluoromethylthiolation, Pages 141-179, F. Toulgoat, T. Billard7 - Nucleophilic Di- and Trifluoromethylation of CO and CN Bonds, Pages 181-199, A.D. Dilman8 - Oxidative Trifluoromethylation and Trifluoromethylthiolation, Pages 201-222, F.-L. Qing, X.-H. Xu9 - Catalytic Enantioselective Fluorination, Pages 223-263, R. Thornbury, G. Schäfer, F.D. Toste10 - Development of Electrophilic Trifluoromethylating Reagents, Pages 265-287, T. Umemoto11 - New Nucleophilic Fluoroalkylations, Pages 289-337, G.K.S. Prakash, Z. Zhang12 - Continuous Flow Selective Direct Fluorination Using Fluorine Gas, Pages 339-348, G. Sandford13 - Synthesis of Fluorinated Nitrogen-Containing Compounds Through Superelectrophilic Activation in Superacid HF/SbF5∗, Pages 349-388, S. Thibaudeau, H. Carreyre, A. Mingot14 - Visible Light–Induced (Per)fluoroalkylation by Photoredox Catalysis, Pages 389-426, G. Dagousset, A. Carboni, G. Masson, E. Magnier15 - Synthesis of Side Chain Fluorinated Amino Acids and Their Effects on the Properties of Peptides and Proteins, Pages 427-464, S. Vukelić, J. Moschner, S. Huhmann, R. Fernandes, A.A. Berger, B. Koksch16 - Ionic Liquids and