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Colloid and Interface Science VOL. V BiocoUoids, Polymers, Monolayers, Membranes, and General Papers EDITED BY MILTON KERKER Clarkson College of Technology Potsdam, New York Academic Press Inc· New York San Francisco London 1976 A Subsidiary of Harcourt Brace Jovanovich, Publishers COPYRIGHT © 1976, BY ACADEMIC PRESS, INC. ALL RIGHTS RESERVED. NO PART OF THIS PUBLICATION MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM OR BY ANY MEANS, ELECTRONIC OR MECHANICAL, INCLUDING PHOTOCOPY, RECORDING, OR ANY INFORMATION STORAGE AND RETRIEVAL SYSTEM, WITHOUT PERMISSION IN WRITING FROM THE PUBLISHER. ACADEMIC PRESS, INC. Ill Fifth Avenue, New York, New York 10003 United Kingdom Edition published by ACADEMIC PRESS, INC. (LONDON) LTD. 24/28 Oval Road, London NW1 Library of Congress Cataloging in Publication Data International Conference on Colloids and Surfaces, 50th, San Juan, P.R., 1976. Colloid and interface science. CONTENTS: v. 2. Aerosols, emulsions, and surfactants.-v. 3. Adsorption, catalysis, solid surfaces, wetting, surface tension, and water.—v. 4. Hydrosols and rheology. [etc.] 1. Colloids—Congresses. 2. Surface chemistry I. Kerker, Milton, II. Title. -Congresses. QD549.I6 1976 54l'.345 76-47668 ISBN 0 - 1 2 - 4 0 4 5 0 5 - 7 (v. 5) PRINTED IN THE UNITED STATES OF AMERICA List of Contributors Arthur W. Adamson, Department of Chemistry, University of Southern California, Los Angeles, California 90007 Paul Ander, Seton Hall University, South Orange, New Jersey 07039 CD. Armeniades, Department of Chemical and Electrical Engineering, Rice University, Houston, Texas 77001 V.A. Arsentiev, visiting professor from Leningrad Mining Institute, The University of British Columbia, Vancouver 8, British Columbia, Canada M. Bender, Chemistry Department, Fairleigh Dickinson University, Teaneck, New Jersey 07666 Frederick A. Bettelheim, Department of Chemistry, Adelphi University, Garden City, Long Island, New York 11530 B.H. Bijsterbosch, Laboratory for Physical and Colloid Chemistry, Agricultural University, De Dreijen 6, Wageningen, The Netherlands Fred W. Billmeyer, Jr., Department of Chemistry, Rensselaer Polytechnic Institute, Troy, New York 12181 Martin Blank, Department of Physiology, College of Physicians and Surgeons of Columbia University, 630 West 168th Street, New York, New York 10032 D.B. Boyer, Department of Dental Research, Iowa State University, Iowa City, Iowa 52242 C.K. Butts, Departments of Public Health and Biochemistry, University of Oregon Health Sciences Center, Portland, Oregon 97201 J. Chanu, Universite Paris VII, Laboratoire de Thermodynamique des Milieux Ioniques et Biologiques, 2 Place Jussieu, 75221 Paris-Cedex 05, France F.C. Chen, Chemistry Department, State University of New York, Stony Brook, New York 11794 T-H. Chiu, Medical Group, Avco Everett Research Laboratory, Inc., 2385 Revere Beach Parkway, Everett, Massachusetts 02149 ix LIST OF CONTRIBUTORS B. Chu, Chemistry Department, State University of New York, Stony Brook, New York 11794 Paul W. Chun, University of Florida, Gainesville, Florida 32610 Dale H. Cowan, Department of Macromolecular Science, Case Western Reserve University, Cleveland, Ohio 44106 E.L. Cussler, Department of Chemical Engineering, Carnegie-Mellon University, Schenley Park, Pittsburgh, Pennsylvania 15213 Lars Davidsson, The Swedish Institute for Surface Chemistry, Drottning Kristinas vag 45, S-l 14 28 Stockholm, Sweden M. Delmotte, Universite Paris VII, Laboratoire de Thermodynamique des Milieux loniques et Biologiques, 2 Place Jussieu, 75221 Paris-Cedex 05, France J.N. Desai, Physical Research Laboratory, Ahmedabad - 380009, India Richard J. Ditore, University of Florida, Gainesville, Florida 32610 T.E. Dougherty, Chemistry Department, Fairleigh Dickinson University, Teaneck, New Jersey 07666 M.E. Duffey, Departm