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Edited by Andrew B. Hughes Amino Acids, Peptides and Proteins in Organic Chemistry Further Reading Pignataro, B. (ed.) Drauz, K., Gröger, H., May, O. (eds.) Ideas in Chemistry and Molecular Sciences Enzyme Catalysis in Organic Synthesis Advances in Synthetic Chemistry Third, completely revised and enlarged edition 2010 ISBN: 978-3-527-32539-9 3 Volumes 2011 Theophil Eicher, Siegfried Hauptmann and Andreas Speicher ISBN: 978-3-527-32547-4 The Chemistry of Heterocycles Fessner, W.-D., Anthonsen, T. Structure, Reactions, Synthesis, and Applications Modern Biocatalysis 2011 Stereoselective and Environmentally Friendly Reactions ISBN: 978-3-527-32868-0 (Hardcover) ISBN: 978-3-527-32747-8 (Softcover) 2009 Royer, J. (ed.) Lutz, S., Bornscheuer, U. T. (eds.) Asymmetric Synthesis of Nitrogen Heterocycles Protein Engineering Handbook 2009 2009 ISBN: 978-3-527-32036-3 ISBN: 978-3-527-31850-6 Reek, J. N. H., Otto, S. Sewald, N., Jakubke, H.-D. Dynamic Combinatorial Chemistry Peptides: Chemistry and Biology 2010 2009 ISBN: 978-3-527-32122-3 ISBN: 978-3-527-31867-4 Rutjes, F., Fokin, V. V. (eds.) Jakubke, H.-D., Sewald, N. Click Chemistry Peptides from A to Z in Chemistry, Biology and Macromolecular Science A Concise Encyclopedia 2011 ISBN: 978-3-527-31722-6 ISBN: 978-3-527-32071-4 2 Volume Set 2008 ISBN: 978-3-527-32085-1 Nicolaou, K. C., Chen, J. S. Classics in Total Synthesis III New Targets, Strategies, Methods 2011 ISBN: 978-3-527-32958-8 (Hardcover) ISBN: 978-3-527-32957-1 (Softcover) Edited by Andrew B. Hughes Amino Acids, Peptides and Proteins in Organic Chemistry Volume 4 - Protection Reactions, Medicinal Chemistry, Combinatorial Synthesis The Editor Andrew B. Hughes La Trobe University Department of Chemistry Victoria 3086 Australia All books published by Wiley-VCH are carefully produced. Nevertheless, authors, editors, and publisher do not warrant the information contained in these books, including this book, to be free of errors. Readers are advised to keep in mind that statements, data, illustrations, procedural details or other items may inadvertently be inaccurate. Library of Congress Card No.: applied for British Library Cataloguing-in-Publication Data A catalogue record for this book is available from the British Library. Bibliographic information published by the Deutsche Nationalbibliothek The Deutsche Nationalbibliothek lists this publication in the Deutsche Nationalbibliografie; detailed bibliographic data are available on the Internet at http://dnb.d-nb.de. # 2011 WILEY-VCH Verlag & Co. KGaA, Boschstr. 12, 69469 Weinheim, Germany All rights reserved (including those of translation into other languages). No part of this book may be reproduced in any form – by photoprinting, microfilm, or any other means – nor transmitted or translated into a machine language without written permission from the publishers. Registered names, trademarks, etc. used in this book, even when not specifically marked as such, are not to be considered unprotected by law. Composition Thomson Digital, Noida, India Printing and Bookbinding Strauss GmbH, Mörlenbach Cover Design Schulz Grafik Design, Fußgönheim Printed in the Federal Republic of Germany Printed on acid-free paper ISBN: 978-3-527-32103-2 V Contents List of Contributors 1 1.1 1.2 1.2.1 1.2.1.1 1.2.1.1.1 1.2.1.1.2 1.2.1.1.3 1.2.1.2 1.2.1.3 1.2.1.4 1.2.1.4.1 1.2.1.4.2 1.2.1.4.3 1.2.1.4.4 1.2.1.5 1.2.2 1.2.2.1 1.2.2.2 1.2.2.2.1 1.2.2.2