Inorganic Chemistry Metal Carbonyl Chemistry

1 Topics in Current Chemistry Fortschritte der Chemischen Forschung Inorganic Chemistry Metal Carbonyl Chemistry Springer-Verlag Berlin Heidelberg New York 1977 This series presents critical reviews of the present position and future trends in m o d e m chemical research. It is addressed to all research and industrial chemists who wish to keep abreast of advances in their subject. As a rule, contributions are specially commissioned. The editors and publishers will, however, always be pleased to receive suggestions and supplementary information. Papers are accepted for "Topics in Current Chemistry" in English. ISBN 3-540-08290-5 Springer-Verlag Berlin Heidelberg New York ISBN 0-387-08290-5 Springer-Verlag New York Heidelberg Berlin Library of Congress Cataloging in Publication Data. Main entry under title: Inorganic chemistry. Metal carbonyl chemistry. (Topics in current chemistry ; 71) 1. Metal earbonyls--Addresses, essays, lectures. I. Series. QD1.F58 no. 71 [QD411] 540'.8s [547'.05] 77-9034 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically those of translation, reprinting, re-use of illustrations, broadcasting, reproduction by photocopying machine or similar means, and storage in data banks. Under § 54 of the German Copyright Law where copies are made for other than private use, a fee is payable to the publisher, the amount of the fee to be determined by agreement with the publisher. © by Springer-Verlag Berlin Heidelberg 1977 Printed in Germany The use of registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Typesetting and printing: Schwetzinger Verlagsdntckerei GmbH, 6830 Schwetzingen. Bookbinding: Konrad Triltsch, Graphischer Betrieb, 8700 Wtirzburg 2152/3140-543210 Contents Tetranuclear Carbonyl Clusters Paolo Chini and Brian T. Heaton Thermochemical Studies of Organo-Transition Metal Carbonyls and Related Compounds Joseph A. Connor 71 The Vibrational Spectra of Metal Carbonyls Sidney F. A. Kettle 111 Inorganic Applications of X-Ray Photoelectron Spectroscopy William L. Jolly 149 Author Index 26-71 183 Editorial Board: Prof. Dr. Michael J. S. Dewar Department of Chemistry, The University of Texas Austin, TX 78712, USA Prof. Dr. Klaus Harrier Institut fiir Organisehe Chemie der TH Petersenstral~ 15, D-6100 Darmstadt Prof. Dr. Edgar Heilbronner Physikalisch-Chemisches Institut der Universit~it Klingelbergstml~e 80, CH-4000 Basel Prof. Dr. Sh6 It6 Department of Chemistry, Tohoku University, Sendal, Japan 980 Prof. Dr. Jean-Marie Lehn Institut de Chimie, Universit6 de Strasbourg, 4, rue Blaise Pascal, B. P. 296/R8, F-67008 Strasbourg-Cedex Prof. Dr. Kurt Niedenzu University of Kentucky, College of Arts and Sciences Department of Chemistry, Lexington, KY 40506, USA Prof. Dr. Klaus Schiller Institut fiir Physikalisehe Chemie der Universit~it Im Neuenheimer Feld 7, D-6900 Heidelberg 1 Prof. Dr. Georg Wittig Institut fiir Organische Chemie der Universit/it Im Neuenheimer Feld 270, D-6900 Heidelberg 1 Managing Editor: Dr. Friedrich L. Boschke Sprlnger-Verlag, Postfach 105 280, D-6900 Heidelberg 1 Springer-Verlag Postfach 105 280 - D-6900 Heidelberg 1 Telephone (0 62 21) 4 87-1 - Telex 04-61723 Heidelberger Platz 3 • D-1000 Berlin 33 Telephone (0 30) 82 2001 - Telex 01-83319 Springer-Verlag New York Inc. 175, Fifth Avenue . New York, NY 10010 Telephone 47