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Over recent years, no other technique has grown to such importance as that of NMR spectroscopy. It is used in all branches of science where precise structural determination is required and where the nature of interactions and reactions in solution is being studied. Annual Reports on NMR Spectroscopy has established itself as a means for the specialist and non-specialist alike to become familiar with new applications of the technique in all branches of chemistry, including biochemistry, and pharmaceutics. This volume focuses on theoretical aspects of NMR nuclear shielding and on applications of NMR to polymer science. Read more... Abstract: Over recent years, no other technique has grown to such importance as that of NMR spectroscopy. It is used in all branches of science where precise structural determination is required and where the nature of interactions and reactions in solution is being studied. Annual Reports on NMR Spectroscopy has established itself as a means for the specialist and non-specialist alike to become familiar with new applications of the technique in all branches of chemistry, including biochemistry, and pharmaceutics. This volume focuses on theoretical aspects of NMR nuclear shielding and on applications of NMR to polymer science
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ANNUAL REPORTS ON
NMR SPECTROSCOPY
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ANNUAL REPORTS ON
NMR SPECTROSCOPY Edited by
G . A. WEBB Department of Chemistry, University of Surrey, Guildford, Surrey, England
VOLUME 29
ACADEMIC PRESS Harcourt Brace & Company, Publishers London San Diego New York Boston Sydney Tokyo Toronto
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Copyright
01994 ACADEMIC PRESS LIMITED
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A catalogue record for this book is available from the British Library
ISBN 0-12-505329-0 ISSN 0066-4103
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List of Contributors Tetsuo Asakura, Department of Biotechnology, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184, Japan. D. B. Chesnut, P . M . Gross Chemical Laboratory, Duke University, Durham, North Carolina 27708, USA. I-Ssuer Chuang, Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
T. A. Cross, National High Magnetic Field Laboratory, Institute of Molecular Biophysics and Department of Chemistry, Florida State University, Tallahassee, Florida 32306, U S A . Makoto Demura, Department of Biotechnology Tokyo University of Agriculture and Technology, Koganei, Tokyo 184, Japan. Angel C. de Dios, Department of Chemistry, University of Illinois at Urbana-Champaign, 505 South Mathews Avenue, Urbana, Illinois 6I801, USA. Tetsuo Hayashi, Plastics Reseurch Laboratory, Tokuyama Corp. Ltd, 1-1 Harumi-chou, Tokuyama, Yamaguchi 745, Japan. Cynthia J. Jameson Department of Chemistry MIC I l l , University of Illinois at Chicago, 845 W . Taylor, Chicago, Illinois 60607, USA. Gary E. Maciel, Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA. Graeme Moad, CSIRO, Division of Chemicals and Polymers, Private Bag 10, Clayton, Victoria 3168, Australia.
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The NMR chemical shift and the information it can provide on structure and environment is admirably reviewed by Professor C. J. Jameson and Dr A. C. DeDios in the