Supramolecular Control of Structure and Reactivity Editorial Board Founding Editor J.-M. Lehn, College de France, Chimie des Interactions Molkulaires, 11 Place Marcelin Berthelot, 75005 Paris, France Editors J.-P. Behr, UniversitC Louis Pasteur, Institut le Bel, 4 Rue Blaise Pascal, F-67070 Strasbourg, France G. R. Desiraju, University of Hyderabad, School of Chemistry, Hyderabad 500134, India A. D. Hamilton, University of Pittsburgh, Department of Chemistry, Pittsburgh, PA 15260, USA T. Kunitake, Kyushu University, Faculty of Engineering, Hakozaki, Fukuoka 812, Japan D. N. Reinhoudt, University of Twente, Faculty of Chemical Technology, PO Box 217, NL-7500 AE Enschede, The Netherlands J.-P. Sauvage, Universitk Louis Pasteur, Institut le Bel, 4 Rue Blaise Pascal, F-67070 Strasbourg, France Supramolecular Control of Structure and Reactivity Perspectives in Supramolecular Chemistry Volume 3 EDITEDBY ANDREW D. HAMILTON University of Pittsburgh, USA JOHN WILEY & SONS Chichester . New York . Brisbane * Toronto . Singapore Copyright 0 1996 by John Wiley & Sons Ltd, Baffins Lane, Chichester, West Sussex PO19 IUD, England National 01243 779777 International ( + 44) 1243 779777 e-mail (for orders and customer service enquiries):
[email protected] Visit our Home Page on http://www.wiley.co.uk or http://www.wiley.com All Rights Reserved. N o part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise, except under the terms of the Copyright, Designs and Patents Act 1988 or under the terms of a licence issued by the Copyright Licensing Agency, 90 Tottenham Court Road, London, UK W l P 9HE, without the permission in writing of the publisher. Other Wiley Editorial Ofices John Wiley & Sons, Inc., 605 Third Avenue, New York, NY 10158-0012, USA Jacaranda Wiley Ltd, 33 Park Road, Milton, Queensland 4064, Australia John Wiley & Sons (Canada) Ltd, 22 Worcester Road, Rexdale, Ontario M9W ILI, Canada John Wiley & Sons (Asia) Pte Ltd, 2 Clementi Loop #02-01, Jin Xing Distripark, Singapore 129809 Library of Congress Cataloging-in-Publication Data Supramolecular control of structure and reactivity / edited by Andrew D. Hamilton. p. cm--(Perspectives in supramolecular chemistry : v. 3) Includes bibliographical references and index. ISBN 0-471-95920-0 (Cloth) I. Hamilton, 1. Macromolecules. 2. Self-organizing systems. Andrew D. 11. Series. QP801.P64S86 1996 96-944 574.8'84~20 CIP British Library Cataloguing in Publication Data A catalogue record for this book is available from the British Library ISBN 0-471-95920-0 Typeset in 10/12pt Times by Dobbie Typesetting Limited, Tavistock, Devon Printed and bound in Great Britain by Biddles Ltd, Guildford and King's Lynn This book is printed on acid-free paper responsibly manufactured from sustainable forestation, for which at least two trees are planted for each one used for paper production. Contents Contributors vii Preface ix 1 Metal Template Control of Self-Assembly in Supramolecular Chemistry John R. Fredericks and Andrew D. Hamilton 2 A Surv