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The only comprehensive reference covering the properties, synthesis and applications of hyperbranched polymers.Helps the reader gain a better understanding of irregular branching and its relationship to a polymer's properties and potential applications, aiding in the design of highly functional materials.Covers the important theoretical aspects of the topic, as well as summarizing available techniques for characterizing these polymers.Compares hyperbranched polymers with conventional linear polymeric materials as well as perfectly branched dendrimers.Includes perspectives on future challenges in the synthesis and use of hyperbranched polymers in functional materials.
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Hyperbranched Polymers Hyperbranched Polymers Synthesis, Properties, and Applications Edited by Deyue Yan, Chao Gao, and Holger Frey A John Wiley & Sons, Inc., Publication Copyright © 2011 by John Wiley & Sons, Inc. All rights reserved Published by John Wiley & Sons, Inc., Hoboken, New Jersey Published simultaneously in Canada No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http://www.wiley.com/go/permission. Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives or written sales materials. The advice and strategies contained herein may not be suitable for your situation. You should consult with a professional where appropriate. Neither the publisher nor author shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages. For general information on our other products and services or for technical support, please contact our Customer Care Department within the United States at (800) 762-2974, outside the United States at (317) 572-3993 or fax (317) 572-4002. Wiley also publishes its books in a variety of electronic formats. Some content that appears in print may not be available in electronic formats. For more information about Wiley products, visit our web site at www.wiley.com. Library of Congress Cataloging-in-Publication Data: Hyperbranched polymers : synthesis, properties, and applications / edited by Deyue Yan, Chao Gao, Holger Frey. p. cm.– (Wiley series on polymer engineering and technology) Includes index. ISBN 978-0-471-78014-4 (cloth) 1. Dendrimers. 2. Polymers. I. Yan, Deyue. II. Gao, Chao. III. Frey, Holger. TP1180.D45H97 2011 668.9– dc22 2010028351 oBook ISBN: 978-0-470-92900-1 ePDF ISBN: 978-0-470-92899-8 ePub ISBN: 978-0-470-93476-0 Printed in Singapore 10 9 8 7 6 5 4 3 2 1 Contents Preface xiii Contributors xv 1. Promising Dendritic Materials: An Introduction to Hyperbranched Polymers 1.1 1.2 1.3 1.4 Importance of Branching Polymer Architecture 1 Dendritic Polymers 3 Hyperbranched Polymers 1.4.1 1.4.2 1.4.3 1.4.4