E-Book Overview
This volume is a collection of 14 plenary lectures and 25 invited and contributed papers which were presented at the International Symposium on Chemistry of Microporous Crystals (CMPC) held at Sophia University in Tokyo, Japan. The symposium was organized by the Japan Association of Zeolite in collaboration with twelve major academic Japanese societies dealing with the chemistry of microporous crystals. The symposium was attended by over 250 researchers from 13 countries.
The objective of the symposium was to present new horizons and developments in the chemistry and application of natural and synthetic crystalline materials having microporous structures. At this meeting the following trends were noted: new possibilities for highly selective oxidation of hydrocarbon and synthesis of fine chemicals using modified zeolites and metallosilicates; sophisticated syntheses of some valuable hydrocarbons such as 2,6-dimethylnaphthalene and styrene which could not be obtained successfully by conventional catalysts; detailed mechanism of decomposition and aromatization of paraffinic hydrocarbons on zeolitic catalysts; methanol conversion on zeolite catalysts; syntheses of novel wide pore aluminophosphates and their isomorphously substituted porous crystals; detailed analysis of the state of cations in zeolites and metallosilicates; application to direct decomposition of nitric oxide; dynamic behavior of molecules in zeolite pores; chemistry and reaction performance of clay minerals.
This proceedings volume contains thorough reviews and original contributions, each of which includes an extensive list of references. The result is a comprehensive overview of the chemistry of zeolite and zeolite-like crystalline materials and clay minerals, including pillared clays.
E-Book Content
Studies in Surface Science and Catalysis 60 CHEMISTRY
OF MICROPOROUS CRYSTALS
Proceedings of the International Symposium on Chemistry of Microporous Crystals, Tokyo, June 26-29, 1 9 9 0
This Page Intentionally Left Blank
Studies in Surface Science and Catalysis Advisory Editors : B. Delmon and J. T. Yates Vol. 60
CHEMISTRY OF MICROPOROUS CRYSTALS PROCEEDINGS OF THE INTERNATIONAL SYMPOSIUM ON CHEMISTRY OF MICROPOROUS CRYSTALS, TOKYO, JUNE 26-29, 1990 Edited by Tomoyuki lnui
Kyoto University
Seitaro Namba
Tokyo Institute of Technology
Takashi Tatsumi
University of Tokyo
ELSEVIER
KODANSHA 1991
Tokyo
Amsterdam-Oxford-New York-Tokyo
Copublished by KODANSHA LTD., Tokyo and ELSEVIER SCIENCE PUBLISHERS B. V., Amsterdam exclusive sales rzghts in Japan KODANSHA LTD. 12-21, Otowa 2-chome, Bunkyo-ku, Tokyo 112, Japan
U.S. A. and Canada ELSEVIER SCIENCE PUBLISHING COMPANY, INC. 655 Avenue of the Americas, New York, N. Y. 10010, U. S. A.
for the
for the rest of the world
ELSEVIER SCIENCE PUBLISHERS B. V. 25 Sara Burgerhartstraat, P. 0. Box 211, 1000 AE Amsterdam, The Netherlands
ISBN 0-444-98702-9(V0l. 60) ISBN 0-444-41 8 0 1 -6(Series) ISBN 4-06-2051 61 -3(Japan)
Copyright 0 1991 by Kodansha Ltd.
All rights reserved No part of this book may be reproduced in any form, by photostat, microfilm, retrieval system, or any other means, without the written permission of Kodansha Ltd.(except in the case of brief quotation for criticism or review)
PRINTED I N JAPAN
Organization
Organizing Committee CHAIRMAN: Professor H. Tominaga (University of Tokyo) GENERAL SECRETARY: Professor T. Inui (Kyoto University) COMMITTEE: Professor A. Iijima (University of Tokyo) Professor E. Kikuchi (Waseda University) - Symposium Site Arrangements Dr. S. Namba (Tokyo Institute of Technology) - Program and Publications Dr. Y. Nishimura (Catalysts and Chemicals Industries Co.) - Finan