This fourth edition of the highly successful and concise textbook contains about 20 % new data. Now included are chapters on <SUP>19F and <SUP>31P NMR as well as references to important Raman bands. With their unique approach of presenting - in the form of texts, tables, charts, and graphs - a succinct compilation of essential reference data for the interpretation of NMR, IR, UV/Vis, and mass spectra, the authors also provide a hands-on guide for interpreting experimental spectral data and elucidating the structure of the respective compounds behind them.
Besides spectra of common solvents, calibration reagents, and MALDI and FAB MS matrix materials, fragmentation rules for mass spectrometry and UV/Vis spectra of representative compounds are included. The book will benefit students during courses and exercises, and advanced learners may use it to supplement their understanding of extended textbooks on the topic. While only a basic knowledge of spectroscopic techniques is required to use this book, it will serve as a data reference for specialists in the field and will support practitioners routinely faced with the task of interpreting spectral information.
"Practically all teachers in spectroscopy and countless students know these books and work continuously with them." (Magnetic Resonance in Chemistry, 2002, Vol. 40, Issue 3, p. 247)
Structure Determination of Organic Compounds
Ern¨o Pretsch · Philippe B¨uhlmann · Martin Badertscher
Structure Determination of Organic Compounds Tables of Spectral Data
Fourth, Revised and Enlarged Edition
123
Prof. Dr. Ern¨o Pretsch ETH Z¨urich Institute of Biogeochemistry and Pollutant Dynamics Universit¨atsstr. 16 8092 Z¨urich Switzerland
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Prof. Dr. Philippe B¨uhlmann University of Minnesota Dept. of Chemistry 209 Pleasant Street SE., Minneapolis, MN 55455 USA
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Dr. Martin Badertscher ETH Z¨urich Laboratory of Organic Chemistry Wolfgang-Pauli-Str. 10 8093 Z¨urich Switzerland
[email protected]
ISBN 978-3-540-93809-5
e-ISBN 978-3-540-93810-1
DOI 10.1007/978-3-540-93810-1 Library of Congress Control Number: 2009920112 c Springer-Verlag Berlin Heidelberg 2009 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer. Violations are liable to prosecution under the German Copyright Law. The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Cover design: WMXDesign GmbH Printed on acid-free paper 9 8 7 6 5 4 3 2 1 springer.com
Preface
The ongoing success of the earlier versions of this book motivated us to prepare a new edition. While modern techniques of nuclear magnetic resonance spectroscopy and mass spectrometry have changed the ways of data