Polymer Stabilized Magnetite Nanoparticles And Poly(propylene Oxide) Modified Styrene-dimethacrylate

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Magnetic nanoparticles that display high saturation magnetization and high magnetic susceptibility are of great interest for medical applications. Nanomagnetite is particularly desirable because it displays strong ferrimagnetic behavior, and is less sensitive to oxidation than magnetic transition metals such as cobalt, iron, and nickel. For in-vivo applications, it is important that well-defined organic coatings surround the nanomagnetite particles. It is rationalized that this will prevent any aggregation of the nanoparticles in-vivo, and may also enable efficient excretion and protection of the body from toxicity.

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Polymer Stabilized Magnetite Nanoparticles and Poly(propylene oxide) Modified Styrene-Dimethacrylate Networks Linda A. Harris Dissertation Submitted to the Faculty of the Virginia Polytechnic Institute and State University in partial fulfillment of the requirements for the degree of DOCTOR of PHILOSOPHY in CHEMISTRY Approved by: Judy S. Riffle, Chair John G. Dillard John J. Lesko James E. McGrath Thomas C. Ward April 19, 2002 Blacksburg, Virginia Keywords: magnetite, nanoparticles, superparamagnetic, poly(ethylene oxide), carboxylic acid, ferrofluid, colloidal dispersion, structural adhesive, vinyl ester, poly(propylene oxide) dimethacrylate, network Copyright 2002, Harris Polymer Stabilized Magnetite Nanoparticles Linda A. Harris (ABSTRACT) Magnetic nanoparticles that display high saturation magnetization and high magnetic susceptibility are of great interest for medical applications. Nanomagnetite is particularly desirable because it displays strong ferrimagnetic behavior, and is less sensitive to oxidation than magnetic transition metals such as cobalt, iron, and nickel. For in-vivo applications, it is important that well-defined organic coatings
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