E-Book Overview
A contemporary compilation of recent achievements in organometallic chemistry
The prestigious International Conference on Organometallic Chemistry (ICOMC) was launched in 1963, providing a forum for researchers from around the world to share their findings and explore new paths to advance our knowledge and application of organometallic chemistry. The 25th ICOMC, held in Lisbon in 2012, gathered more than 1,200 participants from 54 countries. This volume celebrates the 25th Silver Edition and the 50th Gold Year of the ICOMC.
Featuring contributions from invited 25th ICOMC speakers, Advances in Organometallic Chemistry and Catalysis highlights recent achievements and new and emerging areas of research in the field. Its seven sections cover:
- Activation and Functionalization of Carbon Single Bonds and Small Molecules
- Organometallic Synthesis and Catalysis
- Organometallic Polymerization Catalysis
- Organometallic Polymers and Materials
- Organometallic Chemistry and Sustainable Energy
- Bioorganometallic Chemistry
- Organometallic Electrochemistry
Chapters discuss fundamental underlying concepts, offer illustrative examples and cases, and explore future avenues for continued research. Readers will discover basic principles and properties of organometallic compounds, reaction mechanisms, and detailed descriptions of current applications. Collectively, these chapters underscore the versatility, richness, and potential of modern organometallic chemistry, including its interrelationships with other scientific disciplines.
All the contributions are extensively referenced, providing a gateway to the most important original research papers and reviews in organometallic chemistry. Presenting a contemporary understanding of organometallic chemistry and its many applications, Advances in Organometallic Chemistry and Catalysis is recommended for all researchers in the field, from students to advanced investigators.Content: Chapter 1 Organometallic Complexes as Catalysts in Oxidation of CH Compounds (pages 1–13): Georgiy B. Shul'pin Chapter 2 Toward Functionalization of Alkanes under Environmentally Benign Conditions (pages 15–25): Armando J. L. Pombeiro Chapter 3 Self‐Assembled Multicopper Complexes and Coordination Polymers for Oxidation and Hydrocarboxylation of Alkanes (pages 27–38): Alexander M. Kirillov, Marina V. Kirillova and Armando J. L. Pombeiro Chapter 4 Activation of C–O and C–F Bonds by Pincer–Iridium Complexes (pages 39–57): Jason Hackenberg, Karsten Krogh‐Jespersen and Alan S. Goldman Chapter 5 Functionalization of sp2 and sp3 Carbon Centers Catalyzed by Polyoxometalates and Metalloporphyrins (pages 59–71): Mário M. Q. Simões, Isabel C. M. S. Santos, Maria Graça P. M. S. Neves, Ana M. V. Cavaleiro and José A. S. Cavaleiro Chapter 6 Quasi‐Borinium Cation Based on Cobalt Bis(Dicarbollide): Its Lewis Acidity and C–H and C–X Bond Activation (pages 73–79): V. I. Bregadze, I. B. Sivaev, I. D. Kosenko, I. A. Lobanova, Z. A. Starikova and I. A. Godovikov Chapter 7 Transition‐Metal‐Promoted Functionalization of Carboranes (pages 81–96): Zaozao Qiu and Zuowei Xie Chapter 8 Weak Interactions and M–H Bond Activation (pages 97–109): Elena Shubina, Natalia Belkova, Oleg Filippov and Lina Epstein Chapter 9 Complexes with Protic N‐Heterocyclic Carbene (NR,NH‐NHC) Ligands (pages 111–132): F. Ekkehardt Hahn Chapter 10 Cyclopentadienyl‐Functionalized N‐Heterocyclic Carbene Complexes of Iron and Nickel: Catalysts for Reductions (pages 133–143): Beatriz Royo Chapter 11 Palladium‐(Acyclic Diaminocarbene) Species as Alternative to Palladium‐(Nitrogen Heterocyclic Carbenes) in Cross‐Coupling Catalysis (pages 145–155): Vadim P. Boyarskiy, Konstantin V. Luzyanin and Vadim Yu. Kukushkin Chapter 12 Synthesis of Metallocenes Via Metathesis in Metal Coordination Spheres (pages 157–17