In-situ Small-angle X-ray Scattering Investigation Of Transient Nanostructure Of Multi-phase Polymer Materials Under Mechanical Deformation

E-Book Overview

The results in this dissertation set the ground to answer a fundamental question in data-driven polymer material science: "Why don't prepared composites show less fatigue than the pure plastics?" A simultaneous analysis of mechanical testing and small angle X-Ray scattering from the DESY source in Hamburg has been applied to approach this question, which is also central to the European research project "Nanotough", and the results are clearly presented in this book. The evolution of the materials structure is visualized and quantitatively analyzed from exhaustive sequences of scattering images. Three different classes of polymer composites are presented as typical and illustrative examples. The obtained results illustrate that the interactions of their components can cause unpredictable structural effects, ultimaltely leading to a weakening of the material, where a reinforcement was expected.


E-Book Content

Springer Theses Recognizing Outstanding Ph.D. Research For further volumes: http://www.springer.com/series/8790 Aims and Scope The series ‘‘Springer Theses’’ brings together a selection of the very best Ph.D. theses from around the world and across the physical sciences. Nominated and endorsed by two recognized specialists, each published volume has been selected for its scientific excellence and the high impact of its contents for the pertinent field of research. For greater accessibility to non-specialists, the published versions include an extended introduction, as well as a foreword by the student’s supervisor explaining the special relevance of the work for the field. As a whole, the series will provide a valuable resource both for newcomers to the research fields described, and for other scientists seeking detailed background information on special questions. Finally, it provides an accredited documentation of the valuable contributions made by today’s younger generation of scientists. Theses are accepted into the series by invited nomination only and must fulfill all of the following criteria • They must be written in good English. • The topic should fall within the confines of Chemistry, Physics, Earth Sciences, Engineering and related interdisciplinary fields such as Materials, Nanoscience, Chemical Engineering, Complex Systems and Biophysics. • The work reported in the thesis must represent a significant scientific advance. • If the thesis includes previously published material, permission to reproduce this must be gained from the respective copyright holder. • They must have been examined and passed during the 12 months prior to nomination. • Each thesis should include a foreword by the supervisor outlining the significance of its content. • The theses should have a clearly defined structure including an introduction accessible to scientists not expert in that particular field. Ahmad Zeinolebadi In-situ Small-Angle X-ray Scattering Investigation of Transient Nanostructure of Multi-phase Polymer Materials Under Mechanical Deformation Doctoral Thesis accepted by the University of Hamburg, Germany 123 Author Dr. Ahmad Zeinolebadi Institute of Technical and Macromolecular Chemistry University of Hamburg Hamburg Germany Supervisor Prof. Dr. Norbert Stribeck Institute of Technical and Macromolecular Chemistry University of Hamburg Hamburg Germany Present address Polymer Consult Buchner GmbH Hamburg Germany ISSN 2190-5053 ISBN 978-3-642-35412-0 DOI 10.1007/978-3-642-35413-7 ISSN 2190-5061 (electronic) ISBN 978-3-642-35413-7 (eBook) Springer Heidelberg New York Dordrecht London Library of Congress Control Number: 2012954554  Springer-Verlag Berlin Heidelberg 2013 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the
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