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1. K. Zamaraev, R. Khairutdinov: Photoinduced Electron Tunneling Reactions in Chemistry and Biology 2. P. Suppan: The Marcus Inverted Region 3. H.D. Roth: Structure and Reactivity of Organic Radical Cations
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6 3 Topics in Current Chemistry
Photoinduced Electron Transfer IV Editor: J. Mattay With contributions by R. E Khairutdinov, H. D. Roth, P. Suppan, K. I. Zamaraev
With 81Figures and 14Tables
Springer-Verlag Berlin Heidelberg NewYork London Paris Tokyo Hong Kong Barcelona Budapest
This series presents critical reviews of the present position and future trends in m o d e r n chemical research. It is addressed to all research and industrial chemists w h o wish to keep abreast of advances in their subject. As a rule, contributions are specially commissioned. The editors and publishers will, however, always be pleased to be receive suggestions and supplementary information. Papers are accepted for "Topics in Current Chemistry" in English.
ISBN 3-540-55117-4 Springer-Verlag Berlin Heidelberg New York ISBN 0-387-55117-4 Springer-Verlag New York Berlin Heidelberg
Library of Congress Catalog Card Number 74-644622 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag. Violations are liable for prosecution under the German Copyright Law. © Springer-Verlag Berlin Heidelberg 1992 Printed in Germany The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Typesetting: Th. Miintzer, Bad Langensalza; Printing: Heenemann, Berlin; Binding: Liideritz & Bauer, Berlin 51/3020-5 4 3 2 1 0 -- Printed on acid-free paper
Guest Editor Prof. Dr. Jochen Mattay Organisch-Chemisches Institut, Westf'~ilische Wilhelms-Universit/it Miinster, Orl6ansring 23, D-4400 Miinster
Editorial Board Prof. Dr, Michael d. S, Dewar
Department of Chemistry, The University of Texas Austin, TX 78712, USA
Prof. Dr. Jack D. Dunitz
Laboratorium fiir Organische Chemie der Eidgen6ssischen Hochschule Universit~itsstraSe 6/8, CH-8006 Ziirich
Prof. Dr. Klaus Harrier
Institut fiir Organische Chemie der TH Petersenstral~e 15, D-6100 Darmstadt
Prof. Dr. ~qh6 It6
Faculty of Pharmaceutical Sciences Tokushima Bunri University Tokushima 770/Japan
Prof. Dr. Jean-Marie Lehn
Institut de Chimie, Universit6 de Strasbourg, 1, rue Blaise Pascal, B. P. Z 296/R8, F-67008 Strasbourg-Cedex
Prof. Dr. Kurt Niedenzu
University of Kentucky, College of Arts and Sciences Department of Chemistry, Lexington, KY 40506, USA
Prof. Dr. Kenneth N. Raymond
Department of Chemistry, University of California, Berkeley, California 94720, USA
Prof. Dr. Charles W. Rees
Hofmann Professor of Organic Chemistry, Department of Chemistry, Imperial College of Science and Technology, South Kensington, London SW7 2AY, England
Prof. Dr. Joachim Thiem
Institut fiir Organische Chemie, Universitfit Hamburg Martin-Luther-King-Platz 6, 2000 Hamburg 13, FRG
Prof. Dr. Fritz Viigtle
Institut ffir Organische Chemic und Biochemie der Universit/it, Gerhard-Domagk-Str. 1, 5300 Bonn 1, FRG
Preface to the Series on Pho