E-Book Overview
This is the first book to focus on the latest developments in hyphenated techniques using supercritical fluids. The advantages of SFC in hyphenation with various detection modes, such as FTIR, MS, MPD and ICP and others are clearly featured throughout the book. Special attention is paid to coupling of SFE with GC or SFC. In this edited volume, chapters are written by leading experts in the field. The book will be of interest to professionals in academia, as well as to those researchers working in an industrial environment, such as analytical instrumentation, pharmaceuticals, agriculture, food, petrochemicals and environmental.
E-Book Content
JOURNAL OF CHROMATOGRAPHY UBRARY- volume 53
hyphenated techniques in supercritical fluid ch rorna tograph y and extraction
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JOURNAL OF CHROMATOGRAPHY LIBRARY-volume
53
hyphenated techniques in supercritical fluid chroma tograph y and extraction edited b y
School of Materials Science, Toyohashi University of Technology, Toyo hashi, Japan
ELSEVIER Amsterdam -London
-New York-Tokyo
1992
ELSEVIER SCIENCE PUBLISHERS B.V. Sara Burgerhartstraat 25 P.O. Box 21 1,1000 AE Amsterdam,The Netherlands
ISBN 0-444-88794-6
0 1992 Elsevier Science Publishers B.V. All rights reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, withoutthe prior written permission of the publisher, Elsevier Science Publishers B.V., Copyright & Permissions Department, P.O. Box 521,1000 A M Amsterdam,The Netherlands. Special regulations for readers in the U.S.A. -This publication has been registered with the Copyright Clearance Center Inc. (CCC), Salem, Massachusetts. Information can be obtained from the CCC about conditions under which photocopies of parts of this publication may be made i n the U.S.A. All other copyright questions, including photocopying outside of the U.S.A., should be referred to the copyright owner, Elsevier Science Publishers B.V., unless otherwise specified. No responsibility is assumed by the publisher for any injury and/or damage to persons or property as a matter of products liability, negligence or otherwise, or from any use or operation of any methods, products, instructions or ideas contained in the material herein. This book is printed on acid-free paper. Printed in the Netherlands
V
Contents Preface
vii
Contributors
ix
Chapter 1 General Detection Problems in SFC by Herbert H.HiII and David A.Atkinson
1
Chapter 2
Chapter 3 Chapter 4
Fourier Transform Ion Mobility Spectrometry for Detection after SFC by Herbert H.Hill and Edward E.Tarver Advances in Capillary SFC-MS by J.David Pinkston and Donald J.Bowling
25
Advances in Semi Micro Packed Column SFC and Its Hyphenation by Makoto Takeuchi and Toshinori Saito
47
Chapter 5 Flow Cell SFC/FT-IR by Larry T.Taylor and Elizabeth M.Calvey Chapter 6
Chapter 7
SFC/FT-IR Measurements Involving Elimination of the Mobile Phase by Peter RGriffiths, Kelly LNorton and Anthony S.Bonanno Practical Applications of SFC-FTIR by Keith D.Bartle, Anthony AClifford and Mark W.Raynor
Chapter 8 Recycle Supercritical Fluid Chromatography On-line Photodiode-Array Multiwavelength UV/VIS Spect ro rnetry/lR Spectrometry /Gas chromatography by Muneo Saito and Yoshio Yamauchi Chapter 9
9
Inductively Coupled Plasma Atomic Emission Spectrometric Detection in Supercritical Fluid Chromatography by Kiyokatsu Jinno
65
83
103
129
151
Chapter 10 Microwave Plasma Detection in SFC by Debra R.Luffer an