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6 Topics in Current Chemistry Fortschritte der Chemischen Forschung Aspects of Molybdenum and Related Chemistry Springer-Verlag Berlin Heidelberg New York 1978 This series presents critical reviews of the present position and future trends in m o d e m chemical research. It is addressed to all research and industrial chemists who wish to keep abreast of advances in their subject. As a rule, contributions are specially commissioned. The editors and publishers Will, however, always be pleased to receive suggestions and supplementary information. Papers are accepted for "Topics in Current Chemistry"in English. ISBN 3-540-08986-1 Springer-VerlagBerlin Heidelberg New York ISBN 0-387-08986-1 Springer-Vcrlag New York Heidelberg Berlin Librar) of Congress Cataloging in Publication Data. Main entry under title: Aspects of molybdenum and related chemistry. (Topics in current chemistry ; 76) Bibliography: p. Includes index. CONTENTS: Tsigdinos, G. A. Heteropoly compounds of molybdenum and tungsten.- Tsigdinos, G. A. Inorganic sulfur compounds of molybdenum and tungsten - their preparation, structure, and properties. [etc.] 1. Molybdenum compounds-Addresses, essays, lectures. I. Tsigdinos, George A., 1929- Heteropoly compounds of molybdenum and tungsten. 1978. II. Tsigdinos, George A., 1929- Inorganic sulfur compounds of molybdenum and tungsten. 1978. III. Mob, G/inter, 1929- High temperature sulfide chemistry. 1978. IV. Series. QD1.F58 vol. 76 [QDlgl.M7] 540'.8s [546'.534'2] 78-13469 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically those of translation, reprinting, re-use of illustrations, broadcasting, reproduction by photocopying machine or similar means, and storage in data banks. Under § 54 of the German Copyright Law where copies are made for other than private use, a fee is payable to the publisher, the amount of the fee to be determined by agreement with the publisher. © by Springer-Verlag Berlin Heidelberg 1978 Printed in Germany The use of registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Typesetting and printing: Schwetzinger Verlagsdruckerei GmbH, 6830 Schwetzingen. Bookbinding: Konrad Triltsch, Graphischer Betrieb. 8700 Wiirzburg 2152/3140-543210 Contents Heteropoly Compounds of Molybdenum and Tungsten George A_. Tsigdinos Inorganic Sulfur Compounds of Molybdenum and Tungsten~i'heir Preparation, Structure, and Properties George A. Tsigdinos 65 High-Temperature Metal Sulfide Chemistry Gtinter Moh Author Index 26-76 107 153 Editorial Board: Prof. Dr. Michael J. S. Dewar Department of Chemistry, The University of Texas Austin, TX 78712, USA Prof. Dr. Klaus Hafner Institut fiir Organische Claemie der TH PetersenstraBe 15, D-6100 Darmstadt Prof. Dr. Edgar Heilbronner Physikalisch-Chemisehes Institut der Universit~it KlingelbergstraBe 80, CH-4000 Basel Prof. Dr. ShO It6 Department of Chemistry, Tohoku University, Sendai, Japan 980 Prof. Dr. Jean-Marie Lehn Institut de Chimie, Universit6 de Strasbourg, 1, rue Blaise Pascal, B. P. 296/R8, F-67008 Strasbourg-Cedex Prof. Dr. Kurt Niedenzu University of Kentucky, College of Arts and Sciences Department of Chemistry, Lexington, KY 40506, USA Prof. Dr. Charles W. Rees Hofmann Professor of Organic Chemistry Department of Chemistry, Imperial College of Science and Technology, South Kensington, London SW7 2AY, England Prof. Dr. Klaus Sch~fer Institut fiir Physikalische Chemie der Universit~it Im Neue