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Scientific Editor: Ing. Jifi Stamberg, CSc. Reviewers : Ing. Ferdinand Dubsky, CSc. Ing. Jifi Alexa, CSc. Published in co-edition with A C A D E M I A- Publishing House of the Czechoslovak Academy of Sciences, Prague Distribution of this book is being handled by the following publishers for the U. S. A. and Canada Elsevier Science Publishing Co., Inc., 52 Vanderbilt Avenue New York, New York 10017 for the East European Countries, China, Northern Korea, Cuba, Vietnam and Mongolia Academia, Publishing House of the Czechoslovak Academy of Sciences, Prague for all remaining areas Elsevier Scientific Publishing Company 1 Molenwerf P.O. Box 211, 1000 AE Amsterdam, T h e Netherlands Library of Congress Cataloging in Publication Data (Revised) Wilson, Cecil Leeburn, ed. Comprehensive analytical chemistry. Includes bibliographies. Contents: v. 1A—1C. Classical analysis. — v. 2C. Electrical methods, physical separation methods.— [etc] — v. 14. Ion exchangers in analytical chemistry; their properties and use in inorganic chemistry. 1. Chemistry. Analytic. I. Wilson, David Woodburn, 1917- joint ed. I I . Svehla, G. I I I . Title. IV. Title: Wilson and Wilson's comprehensive analytical chemistry. QD75 . W75 543 58-10158 ISBN 0-444-99717-2 (Vol. XIV) 0-444-41735-4 (Series) With 54 Illustrations © Milan Marhol, Prague 1982. Translation © Vaclav Vesely, 1982. All rights reserved. N o part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, without the prior written permission of the publishers Printed in Czechoslovakia COMPREHENSIVE ANALYTICAL CHEMISTRY ADVISORY BOARD R. Belcher, PH.D., D.SC, S.F. INST.E., F.R.S.C, Professor Emeritus: Honorary Senior Research Fellow, Faculty of Medicine, University of Birmingham G. den Boef, PH.D. Professor of Analytical Chemistry, University of Amsterdam A. Hulanicki, PH.D. Professor of Chemistry, University of Warsaw J. Inczédy, PH.D., D.SC. Professor of Analytical Chemistry, University of Chemical Engineering, Veszprém H.M.N.H. Irving, M.A., D.PHIL., F.R.S.C. Professor of Inorganic Chemistry, University of Cape Town G. Tölg, PH.D. Professor of Analytical Chemistry, Max-Planck-Institute for Metal Research, Stuttgart D. W. Wilson, M.SC, F.R.S.C. Formerly Head of the Department of Chemistry, City of London Polytechnic EDITORIAL ASSISTANT Alan Robinson, B.A. Department of Pharmacy, The Queen's University of Belfast Wilson and Wilson's COMPREHENSIVE ANALYTICAL CHEMISTRY Edited by G. SVEHLA, PH.D., D.SC, F.R.S.C. Reader in Analytical Chemistry The Queen's University of Belfast VOLUME XIV ION EXCHANGERS IN ANALYTICAL CHEMISTRY. THEIR PROPERTIES AND USE IN INORGANIC CHEMISTRY BY M. MARHOL ELSEVIER SCIENTIFIC PUBLISHING COMPANY AMSTERDAM OXFORD NEW YORK 1982 WILSON AND WILSON'S COMPREHENSIVE ANALYTICAL CHEMISTRY VOLUMES IN THE SERIES Vol. IA Analytical Processes Gas Analysis Inorganic Qualitative Analysis Organic Qualitative Analysis Inorganic Gravimetric Analysis Vol. IB Inorganic Titrimetric Analysis Organic Quantitative Analysis Vol. IC Analytical Chemistry of the Elements Vol. IIA Electrochemical Analysis Electrodeposition Potentiometric Titrations Conductometric Titrations High-frequency Titrations Vol. IIB Liquid Chromatography in Columns Gas Chromatography Ion Exchangers Distillation Vol. IIC Paper and Thin-Layer Chromatography Radiochemical Methods Nuclear Magnetic Resonance and Electron Spin Resonance Methods X-Ray Spectrometry Vol. IID Coulometric Analysis Vol. I l l Elemental Analysis with Minute Samples Standards and Standardization Separations by Liquid Amalgams Vacuum Fusion Analysis of