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JOURNAL OF CHROMATOGRAPHY LIBRARY - volume32 the science of chromatography lectures presented at the A.J. P. Martin honorary symposium, Urbino, May 27-31, 1985 This Page Intentionally Left Blank JOURNAL OF CHROMATOGRAPHY LIBRARY - volume 32 the science of chromatography lectures presented at the A J F! Martin honorary symposium, Urbino, May 2 7-37, 7985 edited by Fabrizio Bruner lstituto d i Scienze Chimiche, Universit; d i Urbino, Piazza Rinascimento 6, 6 1029 Urbino, Italy ELSEVl E R Amsterdam - Oxford - New York - Tokyo 1985 ELSEVIER SCIENCE PUBLISHERS B.V. Molenwerf 1 P.O. Box 21 1,1000 A € Amsterdam, The Netherlands Distributors for the United States and Canada: ELSEVIER SCIENCE PUBLISHING COMPANY INC. 52, Vanderbilt Avenue New York, N Y 10017 ISBN 044442443-1 (Val. 32) ISBN 0444-41616-1 (Series) 0 Elsevier Science Publishers B.V., 1985 All rights reserved. N o part of this publication may ? repro iced, store in a retrieval system or transmitted in any form or b y any means, electronic, mechanical, photocopying, recording or otherwise, without the prior written permission of the publisher, Elsevier Science Publishers B.V:/Science & Technology Division, P.O. Box 330, 1000 A H Amsterdam, The Netherlands. Special regulations for readers in the USA - This publication has been registered with the Copyright Clearance Center Inc. (CCC), Salem, Massachusetts, Information can be obtained from the CCC about conditions under which photocopies of parts of this publication may be made in the USA. All other copyright questions, including photocopying outside of the USA, should be referred t o the publisher. Printed i n The Netherlands. V CONTENTS Journal o f Chromatography L i b r a r y ( o t h e r volumes i n t h e s e r i e s ) Foreword A.J.P. ...... ................................. XI ............................. XV ............................... XVII ............................. XX Martin.. Contributors VII Acknowledgements B. Koppenhoefer and E. Bayer, C h i r a l r e c o g n i t i o n i n gas chromatographic a n a l y s i s o f enantiomers on c h i r a l p o l y s i l o x a n e s ............ 1 ..... 43 K. Biemann, The mass s p e c t r o m e t e r as a d e t e c t o r i n chromatography P.A. L e c l e r c q , C.P.M. S c h u t j e s and C.A. s e n s i t i v e c a p i l l a r y GC/MS. Cramers, Roads t o f a s t e r and more A p p l i c a t i o n o f 50 um columns ........ 55 .. 67 . 87 ....... 111 E. Cremer, H i s t o r y and s p e c i a l A u s t r i a n c o n t r i b u t i o n s t o chromatography L.S. E t t r e , The f u l l u t i l i z a t i o n o f t h e v a r i a b l e s o f o p e n - t u b u l a r columns E. G i l a v , S e l e c t o r s f o r c h i r a l r e c o g n i t i o n i n chromatography P. Rouchon, M. Schoenauer, P. V a l e n t i n and G. Guiochon, Une n o u v e l l e s i m u l a t i o n numerique de l a p r o p a g a t i o n d ' u n s o l u t e dans une colonne de chromat o g r a p h i e e n regime non l i n 6 a i r e : s c h B a de Godounov e t sch6ma a n t i diffuse ................................ 131 H. Hatano, H i s t o r i c a l i n t r o d u c t i o n and g e l p a c k i n g m a t e r i a l s f o r HPLC s e p a r a t i o n o f p r o t e i n s and n u c l e i c a c i d s ................ .. 179 .......... 205 Cs. HorvBth, Displacement chromatography: y e s t e r d a y , today