Handbook of Carbon Nano Materials Volume 1
Synthesis and Supramolecular Systems
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World Scientific Series on Carbon Nanoscience
Handbook of Carbon Nano Materials Volume 1
Synthesis and Supramolecular Systems
Editors
Francis D’Souza Wichita State University, USA
Karl M. Kadish University of Houston, USA
World Scientific NEW JERSEY
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LONDON
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SINGAPORE
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BEIJING
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HONG KONG
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TA I P E I
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CHENNAI
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Published by World Scientific Publishing Co. Pte. Ltd. 5 Toh Tuck Link, Singapore 596224 USA office: 27 Warren Street, Suite 401-402, Hackensack, NJ 07601 UK office: 57 Shelton Street, Covent Garden, London WC2H 9HE
British Library Cataloguing-in-Publication Data A catalogue record for this book is available from the British Library.
HANDBOOK OF CARBON NANO MATERIALS Volume 1: Synthesis and Supramolecular Systems Copyright © 2011 by World Scientific Publishing Co. Pte. Ltd. All rights reserved. This book, or parts thereof, may not be reproduced in any form or by any means, electronic or mechanical, including photocopying, recording or any information storage and retrieval system now known or to be invented, without written permission from the Publisher.
For photocopying of material in this volume, please pay a copying fee through the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, USA. In this case permission to photocopy is not required from the publisher.
ISBN-13 978-981-4327-81-7 (Set) ISBN-10 981-4327-81-6 (Set) ISBN-13 978-981-4350-20-4 (Vol. 1) ISBN-10 981-4350-20-6 (Vol. 1)
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Printed in Singapore.
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Contents
Preface List of Contributors Contents of Volumes 1 and 2
xiii xv xxi
1 / Chemistry with Fullerene Building Blocks Julien Iehl, Maxence Urbani and Jean-François Nierengarten
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1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 2. Fullerene Building Blocks for Porphyrin Synthesis . . . . . . . . . . . . . . . 2 3. Fullerene Building Blocks for Dendrimer Synthesis . . . . . . . . . . . . . . 6 3.1. Divergent synthesis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 3.2. Convergent synthesis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 4. Click Chemistry with Fullerene Building Blocks . . . . . . . . . . . . . . . . 16 4.1. Click chemistry with fullerene mono- and bis-adducts . . . . . . . 16 4.2. Click chemistry with fullerene hexa-adducts. . . . . . . . . . . . . . . 22 5. Conclusions and Perspectives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
2 / New Reactivity in Fullerene Chemistry Marta Izquierdo, Salvatore Filippone, Ángel Martín-Domenech and Nazario Martín 1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2. Regioselective Intramolecular cis-1 Cycloadditions to Fullerenes . . 2.1. Intramolecular nucleophilic addition of phenols . . . . . . . . . . 2.2. Intramolecular nucleo