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PHYSICS: D. L. WEBSTER
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unpublished work by Goodwin and Wilson of the Massachusetts Institute of Technology. In figure 2 the solid line shows the experimentally determined variation with the pressure of the overvoltage of nickel. Similar curves were found for mercury and lead. The dotted line shows the variation as calculated by Equation 2, using the overvoltage at one atmosphere as a basis for computing the values for the other pressures. The difference between these two curves may be explained by an increase of stirring at the lower pressures, since many more bubbles are produced per mol of gas. It appears quite probable, then, that the factor that determines the overvoltage of an electrode at any one pressure is the size of the gaseous nuclei that can cling to it. A number of observers have called attention to the fact that electrodes with low overvoltages are those that have large adsorptive powers. This adsorptive power is undoubtedly related to the attraction of an electrode for a gaseous nucleus. AN APPROXIMATE LAW OF ENERGY DISTRIBUTION IN THE GENERAL X-RAY SPECTRUM BY DAVID L. WEBSTER DEPARTMENT OF PHYSICS, MASSACHUSETTS INSTITUTE OF TECHNOLOGY Communicated by E. H. Hall, April 9, 1919
spectra of X-rays as ordinarily determined there are factors of abin sorption the anticathode, the glass of the tube, the reflecting crystal and the ionized gas, and of efficiency of reflection that are all functions of the frequency. Fortunately, except at the discontinuities of any of these absorptions, the unknown factors vary continuously with frequency, so that the measured intensities in the spectrum represent the energy distribution qualitatively, but by no means quantitatively. The problem of the present paper is to combine other available data in such a way as to find an approximate law of energy distribution, not involving unknown absorption factors, and avoiding also