Electrochemical Kinetics: Theoretical And Experimental Aspects

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• Year: 1,968

• Pages: 789

• Pages In File: 822

• Language: English

• Topic: 296

• Issue: до 2011-01

• Identifier: 012720251X,9780127202518

• Org File Size: 194,899,819

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• Tags: Химия и химическая промышленность Электрохимия

• Toc: Preface to English-Language Edition......Page 3 Contents......Page 5 Introduction......Page 13 1. Electrode and Cell......Page 15 2. Electrode and Cell Potential Difference......Page 16 3. Inner, Outer, and Surface Potentials......Page 18 5. Volta Potential Difference......Page 19 6. Equilibrium Potentials......Page 20 8. Anodic and Cathodic Current, Faraday's Law......Page 21 10. Exchange Current Density......Page 23 B. Equilibrium Potentials......Page 24 11. Change in Free Enthalpy (Gibbs Free Energy) and Cell Voltage......Page 25 12. Temperature Dependence of the Cell Voltage and Generation and Heat in the Galvanic Cell (Peltier Effect)......Page 29 13. The Electrochemical Potential......Page 31 14. Pressure Dependence of the Equilibrium Cell Voltage......Page 33 15. Concentration Dependence of Equilibrium Cell Voltage (General)......Page 34 17. Various Types of Metal/Ion Electrodes......Page 36 18. The Formation of the Potential Difference. Kinetic and Thermodynamic (Nernst's) Concepts......Page 37 19. Concentration Dependence of the Metal/Ion Potential......Page 38 20. The Standard Electrode Potential of Metal/Ion Electrodes......Page 40 21. Concentration Cells with Transport......Page 42 22. Concentration Cells without Transport......Page 44 23. Electrodes of the Second Kind......Page 46 24. The Estabilishment of Redox Potentials......Page 49 25. Concentration Dependence of Redox Potentials......Page 51 26. The Hydrogen Electrode......Page 53 27. Organic Redox Potentials......Page 54 28. The Cause of the Formation of Liquid Junction Potentials......Page 59 29. General Equation for the Liquid Junction Potential......Page 60 30. Liquid Junction Potential at Different Concentrations of Identical Dissolved Substances......Page 61 31. Liquid Junction Potential in the Most General Case......Page 62 i) Henderson's Equation......Page 63 ii) Planck's Equation......Page 64 32. Liquid Junction Potential Under Special Conditions......Page 65 33. Minimizing the Liquid Junction Potential......Page 66 34. Concepts of the Formation of Donnan Potentials with Semi-permeable Membranes and Ion Exchange Surfaces......Page 67 35. The Magnitude of the Donnan Potential Difference......Page 69 36. Membrane Potentials on Ion Exchanger......Page 76 37. Potentials in Membrane Systems......Page 80 38. The Glass Electrode......Page 82 39. The Membrane Electrode......Page 86 40. Theory of the Electrical Double Layer......Page 87 41. Experimental Values of the Double Layer Capacity......Page 93 42. Electrocapillarity......Page 95 i) Experimental Methods for the Determinations of EtaN......Page 102 ii) Interpretation of the Lippmann Potential......Page 104 iii) No Absolute Potential......Page 106 i) Experiment