E-Book Content
Advances in Polymer Science Fortschritte der Hochpolymeren-Forschung Volume 13 Edited by H.-J. CANTOW, Freiburg i. Br. • G. DALL'ASTA, Milano • J. D. FERRY, Madison • H.FuJIxA, Osaka• M.GoRDon, Colchester. W.KERN, Mainz G. NATTA, Milano • S. OKAMLrRA,Kyoto • C. G. OVERBERGER,Ann Arbor W. PgINS, Syracuse. G. V. SCHULZ, Mainz • W. P. SLICHTER,Murray Hill A. J. STAVERMAN,Leiden. J. K. STILLE,Iowa City. H. A. STUART,Mainz With 49 Figures Springer-Verlag Berlin. Heidelberg. New York 1974 Editors Prof. Dr. H.-J. CANTOW, Institut fiir Makromolekulare Chemic der Universitat, 7800 Freiburg i. Br., Stefan-Meier-Str. 31. BRD Prof. Dr. G. DALL'ASTA, Istituto di Chimica, Industriale del Politecnico, Piazza Leonardo da Vinci 32, Milano, Italia Prof. Dr. J. D. FERRY, Department of Chemistry, The University of Wisconsin, Madison 6, Wisconsin 53706, U S A Prof. Dr. H. FUJITA, Osaka University, Department of Polymer Science, Toyonaka, Osaka, Japan Prof. Dr. M. GORDON, University of Essex, Department of Chemistry, Wivenhoe Park, Colchester C 04 3 SQ, England Prof. Dr. W. KERN, Institut fiir Organische Chemic der Universit~it, 6500 Mainz, B R D Prof. Dr. G. NATTA, Istituto di Chimica Industriale del Politecnico, Milano, Italia Prof. Dr. S. OKAMURA,Department of Polymer Chemistry, Kyoto University, Kyoto, Japan Prof. Dr. C. G. OVERBERGER, The University of Michigan, Department of Chemistry, Ann. Arbor, Michigan 48104, U S A Prof. Dr. W. PRINS, Department of Chemistry, Syracuse University, Syracuse, N.Y. 13210, USA Prof. Dr. G. V. S c u u t z , Institut fiir Physikalische Chemic der Universitiit, 6500 Mainz, BRD Dr. W~LLtAMP. SLICHTER, Bell Telephone Laboratories Incorporated, Chemical Physics Research Department, Murray Hill, New Jersey 07971, USA P r o f . D r . A . J . STAVERMAN, Chem. Laboratoria der Rijks-Universiteit, afd. Fysische Chemic I, Wassenaarseweg, Postbus 75, Leiden, Nederland Prof. Dr. J. K. STmLE, University of Iowa, Department of Chemistry, Iowa City, U S A Prof. Dr. H. A. STUART, Institut fiir Physikalische Chemic der Universit~it, 6500 Mainz, BRD I S B N 3-540-06552-0 S p r i n g e r - V e r l a g Berlin - H e i d e l b e r g - N e w Y o r k 1SBN 0-387-06552-0 S p r i n g e r - V e r l a g N e w Y o r k . H e i d e l b e r g • Berlin The use of general descrive names, trade marks, etc. in this publication, even if the former are not especially identified, is not to be taken as a sign that such names, as understood by the Trade Marks and Merchandise Marks Act, may accordingly be used freely by anyone. This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically those of translation, reprinting, re-use of illustrations, broadcasting, reproduction by photocopying, machine or similar means, and storage in data banks. Under § 54 of the German Copyright Law where copies are made for other than private use, a fee is payable to the publisher, the amount to the fee to be determined by agreement with the publisher. © by Springer-Verlag Berlin- Heidelberg 1974. Library of Congress Catalog Card Number 61-642. Printed in Germany. Typesetting and printing: Brfthlsche Universit~tsdruckerei, Gieflen Thermal Analysis of Polymers W. WRASIDLO G u l f E n v i r o n m e n t a l S y s t e m s , Inc., 10955 J o h n J a y H o p k i n s Drive, S a n Diego, C a l i f o r n i a 92121, U S A Contents A. S c o p e of tl~e Rem'ew . . . . . . . . . . . . . . . . . . . . . . . B. E x r e r i m e n t a l M e t h o d s . . . . . . . . . . . . . . . . . . 1. A d i a b a t i c C a l o r i m e t e r s . . . . . . . . . . . . . . . . . 2. Differential T h e r m a l A n a l y s i s a n d Differential C a l o r i m e t r y 3. D i l a t o m e t r y . . . . . . . . . . . . . . . . . . . . . 4. T h e r m o o p t i c a l A n a l y s i s . . . . . . . . . . . .